Alice in Wonderland: Why The Hatter has orange hair?

I think it was just an aesthetic choice. He wanted a bright color, no doubt, and red is the brightest color human hair. Also, red hair has a bit of a reputation in British culture.

Exactly what is hard to put, but being emotional and fighting are often considered red head traits. It is also plausible, but a bit of a stretch, to connect the orange red hair with Cinnibar. Cinnibar is the mineral ore from which mercury is extracted.

Mercury, in turn, was used in felt hat making and poisoned the workers until it was banned. The phrase "mad as a hatter" may have come from this occupational disease. The phrase was around long before Carrol used the notion in Alice; but, we know about the connection between mercury and madness in hattes now so the movie folks could have made the connection with the orange mineral.

I believe he's meant to represent Hamish Ascot, the boy who offered his hand in marriage at the beginning of the film. Both have red hair, and both - I think - represent two very different love interests for Alice in the film. You'll notice plenty of the people at the beginning of the film represent characters later on, reinforcing the rather Oz-like quality of Underland.

It's actually in regards to the mercury used in millinery by some hatters, causing him to be afflicted by the mercury used to cure felts for hats, which would, seeping from his hat, also cause him to go mad.

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