You can attache an additional ENI (Elastic Network Interface) to an instance in your VPC. This way the ELB (Elastic Load Balancer) routes the incoming Internet requests to the web server, and the additional ENI will be used to connect to your 3rd party (or internal) requests ( Management network ).
Really the only way I am aware of doing this is by setting up your instances within a VPC and having a dedicated NAT instance by what all outbound traffic is routed.
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