For all but a few metals the electrical resistance of a metal in the liquid state is greater than in the solid state. This means that solid metals are better conductors than liquid metals. Metals in the solid state are good conductors because the orderly overlapping of orbitals allows for the easy movement of electrons from atom to atom.
In the liquid state the orderly arrangement of atoms is disrupted and the electrons move less easily, producing the greater electrical resistance. Or to put it another way, the resistivity of a metal in the liquid state is greater than in the solid state.
Liquid metals conduct electricity, showing that the metal atoms are free to move in the sea of electrons.
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