Of two rocks with the same composition, texture and porosity, there are multiple factors affecting their rate of weathering. Generally speaking, however, smaller rocks would tend to be mechanically weathered more quickly because they are more prone to transportation by the agents of erosion. This transportation by wind, water and ice exposes the smaller rock to more abrasion and fracture which quickens its rate of weathering.
Chemical weathering also occurs more quickly in the smaller rock, as the rate of chemical weathering is directly related to the relationship of surface area to a rock's volume. The higher the surface area in proportion to mass, the quicker the rate of weathering; thus the smaller rock would weather faster.
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