This tint -- known as toning -- is caused by exposure to contaminants, like dirt, the oil in peoples' fingers, stuff in the air, or from some kind of liquid The contaminant will chemically react with the metal on the coin's surface and cause it to change color.
The gray color matches the average circulated Buffalo, with traces of lustre. The coin was harshly cleaned long ago, and has toned back to an original look. There are cleaning lines.
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