I agree, when a PC freezes, it's most likely an overheat problem and because it's an AMD CPU, the most likely culprit is the Video card. It can also be the Northbridge overheating as well. This would be under Motherboard temp.
AMD CPUs will BSOD when they overheat normally. Intels will slow down to a crawl and possibly freeze. Additionally, like someone else suggested.
If you have a "cheap" 1000W power supply like off of Ebay or something, They are garbage, and a video card voltage problem will also cause a freeze. Take a look at the motherboard voltage readings and make sure the +12v is always above +12v (not 11.8v or anything like that).
Check the event viewer for further info. There should be info in there telling you what the reason is. Also clicking on the white flag on the taskbar to open Action Center, expand 'Maintenance' and click on 'View reliability history' to see.
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