How can the Diamond display be used on an RGB or color-difference (4:2:2) format to detect when the composite NTSC/PAL signal may exceed it's limits?

This cannot be done. Colors that exceed a predetermined NTSC composite limit are superimposed with those that do not on the Diamond display. They do cluster in the upper-left of the upper diamond and lower-left of the lower diamond but this is of little use.

However, there are several alternatives for determining composite signal limit violations when producing in RGB or Y, Cb, Cr. More.

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