Cayenne pepper definitely adds a lot of personality to a dish. It is used frequently in Cajun, Creole, Spanish, Mexican, Szechuan, Thai, and East Indian recipes. The heat actually comes from the pith, the membrane on which the seeds grow.
The oils from the pith seep down over the seeds, causing them to become hot as well. To decrease the heat of fresh peppers, you can cut them lengthwise and slice out the pith and seeds.
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