What is Pitting Corrosion?

A metal can corrode without being in contact with another metal. In this case different areas of the metal take on different electrical potentials. This can occur because of variations in the metal metallurgical properties or because of variations in the surface oxide layer, such as a break, thinning, inclusion like mill scale, contaminant like dirt, etc. In pitting corrosion the metal at the top of the pit has access to the oxygen in the air and becomes the cathode.

At the bottom of the pit oxygen is depleted and the metal becomes the anode. The deeper the pit is the less the oxygen available at the bottom and the corrosion rate increases. Figure 2 shows the mechanism of pitting corrosion.

Composition rich in chromium and particularly molybdenum and nitrogen display higher resistance to this mode of corrosion. Solution of ferric chloride is used for laboratory testing of pitting corrosion. More.

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