Microwave ovens heat and cook things put in them via the action of microwaves. Microwaves are a high frequency form of electromagnetic energy, and the frequency of the radiation (about 2.45 GHz) is such that the molecules in foods actually absorb some of the radiation. This dielectric heating causes the appearance of thermal energy within the atoms and molecules of the things put into the cavity (the cooking area) of the oven On a molecular level, the structure of groups of atoms often leaves a molecule with a "slightly positive" side and a "slightly negative" side, or, said another way, a weak electrical two-pole structure -- a dipole.
The microwave energy acts on the dipole (causing it to "resonate" or "vibrate" with the microwave) and transfers energy into the molecular structure. This energy is "tanslated" into the thermal energy (heat) that we desire when we "nuc" something in the oven.
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