Which atom will form the most polar bond with the greatest degree of ionic bonding when bonding with sodium?

A because fluorine is the most electronegative.

Fluorine, the most electronegative element of all, forms the most ionic bond with sodium. Electornegativity difference for these elements is: F = 3.05, Cl =2.23, Br = 2.03, I = 1.73. All are ionic but the Na-I bond is just barely on the ionic side of the bond spectrum - maybe 53% - 57% ionic.

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